Fix a typo in a code block in the User Guide (#3462)

Author: bryant1410

docs/user_guide.rst

@@ -51,7 +51,7 @@ these. The canonical file for this is either a ``tox.toml`` or ``tox.ini`` file.
 
        .. code-block:: ini
 
-           [tox]
+            [tox]
             requires =
                 tox>=4
             env_list = lint, type, 3.1{3,2,1}